城市生活垃圾焚烧炉渣对水体中磷的去除效果

    Study on phosphorus removal from aqueous solution with urban incinerator slag

    • 摘要: 城市生活垃圾焚烧炉渣对水体中的磷有较好的去除效果,当初始磷浓度低于200 mg/L 时,炉渣对磷的去除率接近100%;当初始磷浓度为800 mg/L 时,炉渣对磷的去除率接近60%。炉渣对磷的吸附符合Langmuir 和Freundlich 等温吸附模型,相关系数均达显著水平。Langmuir 吸附等温线模拟炉渣的吸附磷性能优于Freundlich 模型,根据Langmuir方程计算出炉渣对磷的理论饱和吸附量为26 162 mg/kg。炉渣对磷的吸附受pH 值的变化影响不大,磷的解析率低,且其重金属浸出浓度低,环境安全性能优良。综上所述,生活垃圾焚烧炉渣是一种较为理想的除磷吸附剂。

       

      Abstract: Urban waste incinerator slag showed good performance in dephosphorization. When initial phosphate concentration was less than 200 mg/L, the dephosphorization rate was nearly 100%, and the figure was nearly 60% at initial concentration of 800 mg/L.Langmuir and Freundlich isotherms were found to fit the data of phosphorus adsorption onto incinerator slag well at a significant level.And phosphorus adsorption was best described by the Langmuir model. Based on the Langmuir model, the maximum phosphorus adsorption capacities of incinerator slag was 26 162 mg/kg. The capacity of phosphorus adsorption was not affected by pH value, and it had a lower desorbility rate, and the heavy metal ion concentrations of the leachate of the incinerator slag were low. The results showed that urban waste incinerator slag was a good choice for removing phosphorus from aqueous solution.

       

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