保湿型高粘附缓释叶面肥的制备及性能研究

    Research on Preparation and Properties of Moisturizing Highly-adhesive Slow-release Foliar Fertilizer

    • 摘要:
      目的 研制粘附性能、吸水性能、缓释性能优异,具有半互穿聚合物网络结构的保湿型高粘附缓释叶面肥。
      方法 采用聚乙烯醇(PVA)和丙烯酸(AA)为原料制备吸水树脂,利用半互穿网络技术将尿素醛穿插到吸水保水网络中,制备得到保湿型高粘附缓释叶面肥,研究聚乙烯醇与丙烯酸质量比(mPVA/mAA)、交联剂加入量对叶面肥吸水性能的影响,以及吸水树脂加入量对叶面肥粘附性能、缓释性能的影响。
      结果 当聚乙烯醇与丙烯酸的质量比为1 ︰ 2、交联剂加入量为0.5% 时,制备的保湿型高粘附缓释叶面肥具有最大吸水率,在自来水中最大吸水率为68.5 g/g。m(PVA+AA)/mUrea=2 ︰ 1时,叶面肥在包菜叶片的氮、磷保留率分别高达80% 和40%;叶面肥氮磷养分在7~10 d释放达到平衡,缓释性能良好。
      结论 研究结果对于解决目前常规叶面肥粘附性差、无保湿性能、无缓释性能的问题具有十分重要的意义。

       

      Abstract:
      Objective The study aims to develop a moisturizing high-adhesion slow-release foliar fertilizer with a semi-interpenetrating polymer network structure and excellent adhesion, water absorption and slow release properties.
      Method Polyvinyl alcohol (PVA) and acrylic acid (AA) were used as raw materials to prepare water-absorbent resin, and semi-interpenetrating network technology used to interpenetrate urea aldehyde into the water-absorbing and water-retaining network to prepare moisturizing high-adhesion slow-release foliar fertilizer. The effects of mass ratio of polyvinyl alcohol to acrylic acid (mPVA/mAA) and addition amount of cross-linking agent on the water absorption property of foliar fertilizer and the effects of addition amount of water-absorbent resin on the adhesion and slow-release properties of foliar fertilizer were studied.
      Result When mPVA/mAA is 1 ∶ 2 and the addition amount of cross-linking agent is 0.5%, the prepared foliar fertilizer has the maximum water absorption rate, which is 68.5 g/g in tap water. When m(PVA+AA)/ m (Urea) = 2 ︰ 1, the retention rates of nitrogen and phosphorus of foliar fertilizer on cabbage leaves reach 80% and 40%, respectively; the release of nitrogen and phosphorus nutrients of leaf fertilizer achieves balance in 7-10 days, with good slow-release performance.
      Conclusion The research is of great significance to solve the problems of poor adhesion, no water absorption, and no slow-release properties of conventional foliar fertilizers.

       

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